STEALTHTM
MATERIAL SAFETY DATA SHEET
FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CALL CHEMTREC - DAY OR NIGHT 1-800-424-9300
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
FORMULATED FOR:
Loveland Products, Inc. 24-Hour Emergency Phone: 1-800-424-9300
P.O. Box 1286 鈥? Greeley, CO 80632-1286 Medical Emergencies: 1-800-301-7976
U.S. Coast Guard National Response Center: 1-800-424-8802
PRODUCT NAME: STEALTH HERBICIDE
CHEMICAL NAME: Herbicide (Pendimethalin): N- (1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine)
CHEMICAL FAMILY: Dinitroaniline Herbicide
EPA REG. NO.: 34704-868
MSDS Number: 000868-05-LPI MSDS Revisions: New Date Of Issue: 01/07/05 Supersedes: New
2. HAZARDS IDENTIFICATION SUMMARY
KEEP OUT OF REACH OF CHILDREN 鈥? CAUTION 鈥? PRECAUCION - Si usted entiende la etiquette, busque a alguien para que se la explique a
usted en detaile. (If you do not understand this label, find someone to explain it to you in detail.) Harmful if swallowed or absorbed through the skin.
Causes moderate eye irritation. Avoid contact with skin, eyes, or clothing.
This product is a dark amber liquid with moderate aromatic odor. Primary routes of entry are Inhalation, eye contact and skin contact.
NOTE TO PHYSICIAN: Because of increased risk of chemical pneumonia or pulmonary edema caused by aspiration of the hydrocarbon solvent, vomiting
should be induced only under professional supervision.
3. COMPOSITION, INFORMATION ON INGREDIENTS
Chemical Ingredients: Percentage by Weight: CAS No. TLV (Units)
Pendimethalin 37.40 40487-42-1 None Established
Inert Ingredients, contains 62.60
Petroleum Solvent, contains 64742-94-5
3
Naphthalene 91-20-3 50 mg/m
3
Ethylene Dichloride 107-06-2 40 mg/m
4. FIRST AID MEASURES
If swallowed: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow.
Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an
unconscious person.
If in eyes: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty with plenty of water for 15-20 minutes. Call a poison
control center or doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably
mouth to mouth if possible. Call a poison control center or doctor for further treatment advice.
FOR A MEDICAL EMERGENCY INVOLVING THIS PRODUCT CALL: 1-800-301-7976. Have the product container or label with you when calling a poison control
center, or doctor, or when going for treatment
5. FIRE FIGHTING MEASURES
O O
FLASH POINT (掳F/Test Method): 208 F / 97.8 C (Seta flash)
FLAMMABLE LIMITS (LFL & UFL): Not established
EXTINGUISHING MEDIA: Considered non-combustible, use medium appropriate to surrounding fire. Dry chemical, carbon
dioxide, foam, water spray or fog.
HAZARDOUS COMBUSTION PRODUCTS: May include but are not limited to oxides of carbon and oxides of nitrogen.
SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to cool containers exposed to fire. Remain upwind. Avoid breathing smoke. Wear self-
contained breathing apparatus and full protective gear.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors can travel to sources of ignition and flash back.
6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Avoid breathing dusts. Sweep up dry spills immediately and transfer to suitable containers for possible land application according to label use or for
disposal. Check local, state and federal regulations for proper disposal.
CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.
7. HANDLING AND STORAGE
HANDLING: Users should wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing
immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Keep away from children, feed or
foodstuffs, seeds, and other pesticides.
O O O
STORAGE: Do not store below 40 F/4.4 C. Extended storage temperatures below 40 F can result in the formation of crystals on the
O
bottom of the container. If crystallization does occur, store the container on its side at room temperature (70 F). and rock
occasionally until crystals re-dissolve. Do not contaminate water, food or feed by storage or disposal.
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STEALTHTM
MATERIAL SAFETY DATA SHEET
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets with requirements listed in the
Worker Protection Standard (WPS) for agricultural pesticides [40CFR 170.240 (d)(4-6)], the handler PPE
requirements may be reduced or modified as specified in the WPS.
RESPIRATORY PROTECTION: If vapors or dusts exceed acceptable levels, wear a NIOSH approved supplied-air pesticide respirator.
EYE PROTECTION: Chemical goggles or shielded safety glasses.
SKIN PROTECTION: Wear protective clothing: long-sleeved shirts and pants, hat, rubber boots with socks. Wear rubber or chemical-
resistant gloves.
OSHA PEL 8 hr TWA ACGIH TLV-TWA
3 3
Naphthalene 50 mg/m 55 mg/m
3
Ethylene Dichloride 50 ppm 40 mg/m
Personal Protective Equipment (PPE): Applicators and other handlers must wear: long sleeved shirt and long pants, chemical resistant gloves,
such as Barrier Laminate or Viton庐 > 14 mils and shoes plus socks. Follow manufacturer鈥檚 instructions for cleaning and maintaining PPE. If no such
instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR: Dark amber liquid with moderate aromatic odor SOLUBILITY: Emulsifiable
SPECIFIC GRAVITY (Water = 1): 1.06 g/ml BULK DENSITY: 8.85 lbs/gal. pH: 6-7 (2-4% aqueous)
O
VAPOR PRESSURE: Not applicable BOILING POINT: 244 C (extrapolated)
PERCENT VOLATILE (by volume): Not applicable EVAPORATION RATE: Not applicable
Note: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items.
10. STABILITY AND REACTIVITY
STABILITY: Stable CONDITIONS TO AVOID: Excessive heat, open flame, other ignition sources.
INCOMPATIBILITY: Oxidizing agents, strong alkali.
HAZARDOUS DECOMPOSITION PRODUCTS: Including but not limited to oxides of carbon and oxides of nitrogen.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Oral LD50 (rat): 3956 mg/kg Acute Dermal LD50 (rabbit): >2200 mg/kg
Eye Irritation (rabbit): Causes mild irritation Skin Irritation (rabbit): Causes mild irritation
Inhalation LC50 (rat): > 5.35 mg/L (4 HR.) Skin Sensitization (guinea pig): Not a sensitizer
Carcinogenic Potential: None listed in OSHA, NTP, IARC or ACGIH
12. ECOLOGICAL INFORMATION
This product is toxic to fish. Do not apply directly to water, or to area where surface water is present, or to intertidal areas below the mean high water
mark. Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent aquatic sites. Do not contaminate water when cleaning
equipment or disposing of equipment wash water. In case of product spill, sweep up and use as per label instructions or dispose as directed.
Do not apply when weather conditions favor drift from target area. Drift or runoff may adversely affect non-target plants.
13. DISPOSAL CONSIDERATIONS
Do not reuse product containers. Plastic: For 5 gallons and under: Triple rinse (or equivalent), then offer for recycling at an ACRC site (go to
http://www.acrecycle.org/ for locations) or by reconditioning, or puncture and dispose of in a sanitary landfill, or incineration, or, if allowed by state and
local authorities, by burning. If burned, stay out of smoke. Bulk and Minibulk: When the container is empty, replace the cap and seal all openings that
have been opened during use, and return the container to the point of purchase, or to an alternate location designated by the registrant at the point of
purchase of this product. If not returned to the point of purchase or to a designated location, triple rinse or pressure rinse the empty container, then offer
for recycling if available. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Do not
contaminate water, food or feed by storage or disposal.
14. TRANSPORT INFORMATION
DOT Shipping Description: 155 gallons and less: NOT REGULATED BY USDOT
DOT Shipping Description: 155 gallons and more: RQ ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (NAPHTHALENE), 9,
UN3082, III, ERG GUIDE 171
U.S. Surface Freight Classification: COMPOUND, TREE OR WEED KILLING, NOI (NMFC 50320, SUB 2:CLASS: 60)
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STEALTHTM
MATERIAL SAFETY DATA SHEET
15. REGULATORY INFORMATION
NFPA & HMIS Hazard Ratings: NFPA HMIS
1 Health 0 Least 1 Health
1 Flammability 1 Slight 1 Flammability
1 Instability 2 Moderate 1 Reactivity
3 High H PPE
4 Severe
SARA Hazard Notification/Reporting
SARA Title III Hazard Category: Immediate __Y__ Fire __N__ Sudden Release of Pressure __N__
Delayed __N__ Reactive __N__
Reportable Quantity (RQ) under U.S. CERCLA: Naphthalene (CAS: 91-20-3) 100 pounds; Ethylene Dichloride (CAS: 107-06-2) 100 pounds
SARA, Title III, Section 313: Pendimethalin (CAS: 40487-42-1) [TRI Threshold 100 pounds], Naphthalene (CAS: 91-20-3), Ethylene Dichloride (CAS: 107-
06-2)
RCRA Waste Code: Not listed
CA Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer or birth defects or other reproductive
harm.
16. OTHER INFORMATION
MSDS STATUS: New
PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental/ Regulatory Services
Although the information and recommendations set forth herein (hereinafter 鈥淚nformation鈥?) are presented in good faith and believed to be correct, Loveland
Products, Inc., the manufacturer or the seller makes no representations as to the completeness or accuracy thereof. Information is supplied upon the
condition that the persons receiving it will make their own determination as to its suitability for their purposes prior to use.
The product covered by this information sheet is furnished 鈥渁s is鈥? by Loveland Products, Inc., the manufacturer or the seller, and is subject only to the
warranties, if any, that appear on the product鈥檚 label or are otherwise expressly provided herein.
Except as expressly provided on the product鈥檚 label or otherwise provided herein, no warranties, guarantees, or representations of any kind, either express
or implied, or by usage of trade, statutory or otherwise, are made by Loveland Products, Inc., the manufacturer or the seller with regard to the product or
use of the product, including, but not limited to, merchantability, fitness for a particular purpose, use or eligibility of the product for any particular trade
usage.
Except as expressly stated herein, Loveland Products, Inc., the manufacturer or the seller makes no warranty of results to be obtained by use of the
product covered by this information. Buyer鈥檚 or user鈥檚 exclusive remedy, and the total liability of Loveland Products, Inc., the manufacturer or the seller,
shall be limited to damages not exceeding the cost of the product. No agent or employee of Loveland Products, Inc., the manufacturer or the seller is
authorized to amend the terms of this warranty disclaimer or the product鈥檚 label or to make a representation or recommendation different from or
inconsistent with the label of this product.
IN NO EVENT SHALL LOVELAND PRODUCTS, INC., THE MANUFACTURER OR THE SELLER BE LIABLE FOR CONSEQUENTIAL, SPECIAL OR
INDIRECT DAMAGES RESULTING FROM THE USE, HANDLING, APPLICATION, STORAGE OR DISPOSAL OF THIS PRODUCT OR FOR
DAMAGES IN THE NATURE OF PENALTIES AND THE BUYER AND USER WAIVE ANY RIGHT THEY MAY HAVE TO SUCH DAMAGES.
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